Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME

WORLD WIDE WELDING AIR CARBON ARC ELECTRODES

NFPA

PRODUCT USE

Arc metal removal.

SYNONYMS

"arc metal removal"

Section 2 - HAZARDS IDENTIFICATION

CANADIAN WHMIS SYMBOLS

EMERGENCY OVERVIEW

RISK

Harmful: danger of serious damage to health by prolonged exposure through
inhalation.
May cause fire.
Harmful to aquatic organisms.

POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS

SWALLOWED

  Accidental ingestion of the material may be damaging to the health of the individual.  Ingestion of finely divided carbon may produce gagging and constipation. Aspiration does not appear to be a concern as the material is generally regarded as inert and is often used as a food additive. Ingestion may produce a black stool.  A metallic taste, nausea, vomiting and burning feeling in the upper stomach region occur after ingestion of copper and its derivatives. The vomitus is usually green/blue and discolors contaminated skin. Acute poisonings from ingestion are rare due to their prompt removal by vomiting. Should vomiting not occur, or is delayed systemic poisoning may occur producing kidney and liver damage, wide-spread capillary damage, and be fatal; death may occur after relapse from an apparent recovery. Anemia may occur in acute poisoning.  

EYE

  There is some evidence to suggest that this material can causeeye irritation and damage in some persons.  Eyes exposed to carbon particulates may be liable to irritation and burning. These can remain in the eye causing inflammation lasting weeks, and can cause permanent dark dotty discoloration.  

SKIN

  There is some evidence to suggest that this material can cause inflammation of the skin on contact in some persons.  Exposure to copper, by skin, has come from its use in pigments, ointments, ornaments, jewellery, dental amalgams and IUDs and as an antifungal agent and an algicide. Although copper algicides are used in the treatment of water in swimming pools and reservoirs, there are no reports of toxicity from these applications. Reports of allergic contact dermatitis following contact with copper and its salts have appeared in the literature, however the exposure concentrations leading to any effect have been poorly characterised. In one study, patch testing of 1190 eczema patients found that only 13 (1.1%) cross-  reacted with 2% copper sulfate in petrolatum. The investigators warned, however, that the possibility of contamination with nickel (an established contact allergen) might have been the cause of the reaction. Copper salts often produce an itching eczema in contact with skin. This is, likely, of a non-allergic nature.  Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.  

INHALED

  Inhalation may produce health damage*.  Inhalation of vapors or aerosols (mists, fumes), generated by the material during the course of normal handling, may be damaging to the health of the individual.  There is some evidence to suggest that the material can cause respiratory irritation in some persons. The body's response to such irritation can cause further lung damage.  Impurities found in carbons can be toxic, including iodine. Carbon dusts in the air may cause irritation of the mucous membranes, eyes and skin. Coughing, irritation of the upper airways and eye burning may occur.  

CHRONIC HEALTH EFFECTS

  Limited evidence suggests that repeated or long-term occupational exposure may produce cumulative health effects involving organs or biochemical systems.  There has been some concern that this material can cause cancer or mutations but there is not enough data to make an assessment.  There is insufficient evidence to suggest that exposure to carbon black causes increased susceptibility to cancer or other ill effects. Some lung changes can occur after a prolonged period of exposure as well as increased strain on the right side of the heart.