Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME

HB FULLER SUPER GLUE

NFPA

PRODUCT USE

Cyanoacrylate adhesive.

SYNONYMS

"glue Power Bond adhesive"

Section 2 - HAZARDS IDENTIFICATION

CANADIAN WHMIS SYMBOLS

EMERGENCY OVERVIEW

RISK

Irritating to eyes, respiratory system and skin.

POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS

SWALLOWED

  Uncured cyanoacrylates are difficult to swallow as saliva cures the surface of the adhesive with negligible bonding. The cured material is considered to be non-hazardous.  Considered an unlikely route of entry in commercial/industrial environments.  

EYE

  This material can cause eye irritation and damage in some persons.  Exposure to cyanoacrylate vapors can cause discomfort and tears, nasal discharge, and blurred vision. The eyelids may be glued shut. Double vision and corneal scratching may occur.  

SKIN

  This material can cause inflammation of the skin oncontact in some persons.  The material may accentuate any pre-existing dermatitis condition.  Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.  

INHALED

  If inhaled, this material can irritate the throat andlungs of some persons.  In low humidity, cyanoacrylate vapors are irritating to the respiratory system and eyes. High concentrations may cause inflammation of the lungs and other complications. They are much less dangerous in high humidity.  

CHRONIC HEALTH EFFECTS

  Limited evidence suggests that repeated or long-term occupational exposure may produce cumulative health effects involving organs or biochemical systems.  There is some evidence that inhaling this product is more likely to cause a sensitization reaction in some persons compared to the general population.  There is limited evidence that, skin contact with this product is more likely to cause a sensitization reaction in some persons compared to the general population.  Chronic exposure to cyanides and certain nitriles may result in interference to iodine uptake by thyroid gland and its consequent enlargement. This occurs following metabolic conversion of the cyanide moiety to thiocyanate. Thyroid insufficiency may also occur as a result of metabolic conversion of cyanides to the corresponding thiocyanate. Exposure to small amounts of cyanide compounds over long periods are reported to cause loss of appetite, headache, weakness, nausea, dizziness, abdominal pain, changes in taste and smell, muscle cramps, weight loss, flushing of the face, persistent runny nose and irritation of the upper respiratory tract and eyes. These symptoms are not specific to cyanide exposure and therefore the existence of a chronic cyanide toxicity remains speculative. Repeated minor contact with cyanides produce a characteristic rash with itching, papules (small, superficial raised spots on the skin) and possible sensitization. Concerns have been expressed that low-level, long term exposures may result in damage to the nerves of the eye.  Respiratory sensitization may result in allergic/asthma like responses; from coughing and minor breathing difficulties to bronchitis with wheezing, gasping.  Dermatitis may result from prolonged exposures. On repeated and prolonged exposure by skin contact or inhalation, a small proportion of individuals develop allergic sensitivities.