Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME

WHITE KNIGHT SUPER PRIMER AEROSOL

NFPA

PRODUCT USE

Application is by spray atomization from a hand held aerosol pack. An anti corrosive
primer for the protection of steel, wrought iron and all ferrous metals

SYNONYMS

"anti corrosive primer"

Section 2 - HAZARDS IDENTIFICATION

CANADIAN WHMIS SYMBOLS

EMERGENCY OVERVIEW

RISK

Harmful if swallowed.
Possible risk of harm to the unborn child.
Harmful: danger of serious damage to health by prolonged exposure through
inhalation.
Irritating to eyes and skin.
Extremely flammable.
Vapors may cause dizziness or suffocation.
Risk of explosion if heated under confinement.

POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS

SWALLOWED

  Accidental ingestion of the material may be harmful; animal experiments indicate that ingestion of less than 150 gram may be fatal or may produce serious damage to the health of the individual.  Not normally a hazard due to physical form of product.  Considered an unlikely route of entry in commercial/industrial environments.  There is some evidence to suggest that this material can cause, if swallowed once, irreversible damage of organs.  Ingestion of alkyl ethers may produce stupor, blurred vision, headache, dizziness and irritation of the nose and throat. Respiratory distress and asphyxia may result.  Central nervous system (CNS) depression may include general discomfort, symptoms of giddiness, headache, dizziness, nausea, anaesthetic effects, slowed reaction time, slurred speech and may progress to unconsciousness. Serious poisonings may result in respiratory depression and may be fatal.  Considered an unlikely route of entry in commercial/industrial environments. The liquid may produce gastrointestinal discomfort and may be harmful if swallowed. Ingestion may result in nausea, pain and vomiting. Vomit entering the lungs by aspiration may cause potentially lethal chemical pneumonitis.  

EYE

  There is evidence that material may produce eye irritation in some persons and produce eye damage 24 hours or more after instillation. Severe inflammation may be expected with pain. There may be damage to the cornea. Unless treatment is prompt and adequate there may be permanent loss of vision. Conjunctivitis can occur following repeated exposure.  Eye contact with alkyl ethers (vapor or liquid) may produce irritation,redness and tears.  The liquid produces a high level of eye discomfort and is capable of causing pain and severe conjunctivitis. Corneal injury may develop, with possible permanent impairment of vision, if not promptly and adequately treated.  The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis.  

SKIN

  There is some evidence to suggest that this material, on a single contact with skin, can cause irreversible damage of organs.  Skin contact with the material may damage the health of the individual; systemic effects may result following absorption.  There is some evidence to suggest that this material can cause inflammation of the skin on contact in some persons.  Spray mist may produce discomfort.  Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.  Alkyl ethers may defat and dehydrate the skin producing dermatoses. Absorption may produce headache, dizziness, and central nervous system depression.  The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles, scaling and thickening of the skin.  

INHALED

  Inhalation may produce health damage*.  Inhalation of aerosols (mists, fumes), generated by the material during the course of normal handling, may be harmful.  There is some evidence to suggest that this material can cause, if inhaled once, irreversible damage of organs.  Inhalation of toxic gases may cause:  ·  Central Nervous System effects including depression, headache, confusion, dizziness, stupor, coma and seizures;  ·  respiratory: acute lung swellings, shortness of breath, wheezing, rapid breathing, other symptoms and respiratory arrest;  ·  heart: collapse, irregular heartbeats and cardiac arrest;  ·  gastrointestinal: irritation, ulcers, nausea and vomiting (may be bloody), and abdominal pain.  

CHRONIC HEALTH EFFECTS

  Principal route of occupational exposure to the gas is by inhalation.  Limited evidence suggests that repeated or long-term occupational exposure may produce cumulative health effects involving organs or biochemical systems.  There has been some concern that this material can cause cancer or mutations but there is not enough data to make an assessment.  There is some evidence that human exposure to the material may result in developmental toxicity. This evidence is based on animal studies where effects have been observed in the absence of marked maternal toxicity, or at around the same dose levels as other toxic effects but which are not secondary non-specific consequences of the other toxic effects.  Chronic exposure to alkyl ethers may result in loss of appetite, excessivethirst, fatigue,  and weight loss.  Repeated overexposure of liquid to skin can cause cracking and drying. Rabbits exposed for 15 minute periods, daily, 5 days/week for 13 weeks, showed no changes in haematology, gross pathology or histopathology of the lungs, spleen, liver, kidney, lymph nodes, aorta or testes. Rats and rabbits exposed at 50.000 ppm, 7 hours/day,  5 days/week for 90 days, showed narcosis.  Chronic solvent inhalation exposures may result in nervous system impairment and liver and blood changes. [PATTYS].