Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME

WATTYL SIGMA T.C.N. 300 PART A COLOUR RANGE *OBSOLETE*

NFPA

PRODUCT USE

Part B or Hardener of a 2 pack. epoxy coating system. Requires that the two parts be mixed
by hand or mixer before use, in accordance with manufacturers directions. Mix only as much
as is required. Do not return the mixed material to the original containers. Application
is by brush or hand roller and may also be applied by airless spray atomisation. Operators
should be trained in procedures for safe use of this material. The use of a quantity of
material in an unventilated or confined space may result in increased exposure and an
irritating atmosphere developing.Before starting consider control of exposure by
mechanical ventilation.

SYNONYMS

"Part A Coal Tar Epoxy coating colturiet"

Section 2 - HAZARDS IDENTIFICATION

CANADIAN WHMIS SYMBOLS

EMERGENCY OVERVIEW

RISK

May cause CANCER.
HARMFUL - May cause lung damage if swallowed.
Harmful by inhalation and in contact with skin.
Irritating to eyes and skin.
Flammable.
Harmful to aquatic organisms.

POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS

SWALLOWED

  Although ingestion is not thought to produce harmful effects, the material may still be damaging to the health of the individual following ingestion, especially where pre-  existing organ (e.g. liver, kidney) damage is evident. Present definitions of harmful or toxic substances are generally based on doses producing mortality (death) rather than those producing morbidity (disease, ill-health). Gastrointestinal tract discomfort may produce nausea and vomiting. In an occupational setting however, ingestion of insignificant quantities is not thought to be cause for concern.  Considered an unlikely route of entry in commercial/industrial environments.  Ingestion may result in nausea, pain, vomiting. Vomit entering the lungs by aspiration may cause potentially lethal chemical pneumonitis.  

EYE

  This material can cause eye irritation and damage in some persons.  The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis.  

SKIN

  Skin contact with the material may be harmful; systemic effects may resultfollowing absorption.  This material can cause inflammation of the skin oncontact in some persons.  The liquid is discomforting to the skin.  Toxic effects may result from skin absorption.  Epoxy materials may cause allergic and/or contact dermatitis responses, which may occur on exposure or may become apparent only after repeated exposures. Sensitization is possible. Photoallergic dermatitis may result from contact with the material. This type of response can be elicited only in individuals who have been previously allergically sensitized to the chemical agent and appropriate radiation. Photoallergic dermatitis presents, clinically, as an eczematous dermatitis in sun-exposed areas.  Sensitization reactions may appear suddenly after repeatedsymptom free exposures.  Sensitization may result in allergic dermatitis responses includingrash, itching, hives or swelling of extremities.  Bare unprotected skin should not be exposed to this material.  The material may accentuate any pre-existing skin condition.  The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles, scaling and thickening of the skin.  

INHALED

  The material is not thought to produce respiratory irritation (as classified using animal models). Nevertheless inhalation of the material, especially for prolonged periods, may produce respiratory discomfort and occasionally, distress.  Inhalation hazard is increased at higher temperatures.  Inhalation of high concentrations of gas/vapor causes lung irritation with coughing and nausea, central nervous depression with headache and dizziness, slowing of reflexes, fatigue and inco-ordination.  If exposure to highly concentrated solvent atmosphere is prolonged this may lead to narcosis, unconsciousness, even coma and possible death.  Inhalation of vapor may aggravate a pre-existing respiratory condition.  

CHRONIC HEALTH EFFECTS

  There is some evidence that inhaling this product is more likely to cause a sensitization reaction in some persons compared to the general population.  There is sufficient evidence to suggest that this materialdirectly causes cancer in humans.  

  Principal routes of exposure are usually by.  skin contact/absorption inhalation of vapor and inhalation of vapor from the curing material.  Prolonged or continuous skin contact with the liquid may cause defatting with drying, cracking, irritation and dermatitis following.  Chronic solvent inhalation exposures may result in nervous system impairment and liver and blood changes. [PATTYS].  Respiratory sensitization may result in allergic/asthma like responses; from coughing and minor breathing difficulties to bronchitis with wheezing, gasping.  Sensitization may give severe responses to very low levels of exposure, i.e. hypersensitivity. Sensitized persons should not be allowed to work in situations where exposure may occur.